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Dynamic mechanical analysis of single walled carbon nanotubes/polymethyl methacrylate nanocomposite films

机译:单壁碳纳米管/聚甲基丙烯酸甲酯纳米复合薄膜的动态力学分析

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摘要

Dynamic mechanical properties of nanocomposite films with different ratios of single walled carbon nan-otubes/polymethyl methacrylate (SWCNTs/PMMA) are studied. Nanocomposite films of different ratios (0, 0.5, 1.0, and 2.0 weight percent (wt%)) of SWCNTs/PMMA are fabricated by using a casting technique. The morphological and struc-tural properties of both SWCNT powder and SWCNTs/PMMA nanocomposite films are investigated by using a high resolution transmission electron microscope and x-ray diffractometer respectively. The mechanical properties including the storage modulus, loss modulus, loss factor (tanδ) and stiffness of the nanocomposite film as a function of tempera-ture are recorded by using a dynamic mechanical analyzer at a frequency of 1 Hz. Compared with pure PMMA film, the nanocomposite films with different ratios of SWCNTs/PMMA are observed to have enhanced storage moduli, loss moduli and high stiffness, each of which is a function of temperature. The intensity of the tanδ peak for pure PMMA film is larger than those of the nanocomposite films. The glass transition temperature (Tg) of SWCNTs/PMMA nanocomposite film shifts towards the higher temperature side with respect to pure PMMA film from 91.2 ◦C to 99.5 ◦C as the ratio of SWCNTs/PMMA increases from 0 to 2.0 wt%.
机译:研究了单壁碳纳米管/聚甲基丙烯酸甲酯(SWCNTs / PMMA)不同比例的纳米复合薄膜的动态力学性能。通过使用流延技术制备了不同比例(0、0.5、1.0和2.0重量百分比(wt%))的SWCNT / PMMA纳米复合薄膜。分别使用高分辨率透射电子显微镜和X射线衍射仪研究了SWCNT粉末和SWCNTs / PMMA纳米复合膜的形貌和结构性能。通过使用动态机械分析仪以1 Hz的频率记录包括纳米复合膜的储能模量,损耗模量,损耗因子(tanδ)和刚度随温度变化的机械性能。与纯PMMA膜相比,观察到具有不同比例的SWCNT / PMMA的纳米复合膜具有增强的储能模量,损耗模量和高刚度,而每一个都是温度的函数。纯PMMA膜的tanδ峰强度大于纳米复合膜的tanδ峰强度。随着SWCNTs / PMMA的比例从0到2.0 wt%,SWCNTs / PMMA纳米复合膜的玻璃化转变温度(Tg)相对于纯PMMA膜从91.2°C到99.5°C移向更高的温度侧。

著录项

  • 来源
    《中国物理:英文版》 |2015年第10期|1-5|共5页
  • 作者

    Ali Badawi; N. Al-Hosiny;

  • 作者单位

    Department of Physics, Faculty of Science, Taif University, Taif 21974, Saudi Arabia;

    Department of Physics, Faculty of Science, Taif University, Taif 21974, Saudi Arabia;

  • 收录信息 中国科学引文数据库(CSCD);中国科技论文与引文数据库(CSTPCD);
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类
  • 关键词

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