Raman soliton self-frequency shifted to mid-infrared band (λ>2 µm) has been achieved in an air-silica microstructure fiber (MF). The MF used in our experiment has an elliptical core with diameters of 1.08 and 2.48 µm for fast and slow axis. Numerical simulation shows that each fundamental orthogonal polarization mode has two wide-spacedλZDW and theλZDW pairs located at 701/2110 nm and 755/2498 nm along the fast and slow axis, respectively. Using 810-nm Ti:sapphire femtosecond laser as pump, when the output power varies from 0.3 to 0.5 W, the furthest red-shift Raman solitons in both fast and slow axis shift from near-infrared band to mid-infrared band, reaching as far as 2030 and 2261 nm. Also, mid-infrared Raman solitons can always be generated for pump wavelength longer than 790 nm if output pump power reaches 0.5 W. Specifically, with pump power at 0.5 W, the mid-infrared soliton in slow axis shifts from 2001 to 2261 nm when the pump changes from 790 nm to 810 nm. This means only a 20 nm change of pump results in 260 nm tunability of a mid-infrared soliton.
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