Temperature dependence of line parameters of 12C16O2 near 2.004 studied by tunable diode laser spectroscopy

摘要

The absorption spectrum of carbon dioxide at 2.004 μin has been recorded at sample temperatures between 218.0 K and room temperature,by using a high-resolution tunable diode laser absorption spectrometer (TDLAS) combined with a temperature controlled cryogenically cooled absorption cell.The self-,N2-,and air-broadening coefficients for nine transitions of 12C16O2 belonging to the 20012←00001 band in the 4987 cm-1-4998 cm-1 region have been measured at different temperatures.From these measurements,we have further determined the temperature dependence exponents of the pressure-broadening coefficients.To the best of our knowledge,the temperature dependence parameters of the collisional broadening coefficients are reported experimentally for the first time for these nine transitions.The measured halfwidth coefficients and the air temperature dependence exponents of these transitions are compared with the available values reported in the literature and HITRAN 2012 database.Agreements and discrepancies are also discussed.