Zn-Cu-codoped SnO_2 nanoparticles: Structural, optical, and ferromagnetic behaviors

摘要

Zn–Cu-codoped SnO_2 nanoparticles have been synthesized by chemical precipitation method. All nanoparticles are crystalline, with the average size increases from 2.55 nm to 4.13 nm as the calcination temperature increases from 400℃ to 600℃. The high calcination temperature can enhance the crystalline quality and grain growth. The oxygen content decreases with decreasing calcination temperature; at a low temperature of 400℃, Zn–Cu-codoped SnO_2 nanoparticles are in a rather oxygen-poor state having many oxygen vacancies. The optical band gap energies of Zn–Cu-codoped SnO_2 nanoparticles calcined at 400℃ and 600℃ are decreased from 3.93 eV to 3.62 eV due to quantum confinement effects.Both samples exhibit room-temperature ferromagnetism, with a larger saturation magnetization at 400℃ due to the presence of large density of defects such as oxygen vacancies. Zn–Cu-codoped SnO_2 nanoparticles exhibit large optical band gap energies and room temperature ferromagnetism, which make them potential candidates for applications in optoelectronics and spintronics.