Synthesis of an Interrupted AST-Type Zeolitic Imidazolate Framework

摘要

Presented here is a new interrupted AST-type zeolitic imidazolate framework,Zn5(OH)(dmbim)9(H2O)·4(DMF) (1) with cub and interrupted ast cages,which exhibits permanent porosity,high hydrophobicity and strong solid-state photoluminescent properties.More importantly,structural ordered DMF molecules are firmly confined in the-ast cage by strong host-guest interactions.