Effect of Temperature on Phase and Alumina Extraction Efficiency of the Product from Sintering Coal Fly Ash with Ammonium Sulfate☆

摘要

A new developed technology for extracting alumina from coal fly ash was studied in this paper. In this technol-ogy, coal fly ash is first sintered with ammonium sulfate, forming ammonium aluminum sulfate in the resultant product, where alumina can be easily leached without using any strong acid or alkali. The products obtained under different sintering conditions were characterized by X-ray diffractometry. Alumina extraction efficiency of these products was also investigated. The results show that the sintering temperature and time substantially influence the phase composition and alumina extraction efficiency of sintered products, while the heating rate has little influence. The optimal sintering condition is 400 °C for 3 h in air with a heating rate of 6 °C·min?1. Under the optimal sintering condition, the alumina extraction efficiency from as-sintered coal fly ash can reach 85%or more.