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A Novel Composite Electrode of Photocatalyst—TiO2/C Loading on the Surface of the Air (Oxygen) Electrode

机译:一种新型的光催化剂复合电极—TiO2 / C负载在空气(氧气)电极表面

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摘要

The methods for preparing the H2O2 generating air (oxygen) electrode and the composite electrode of photocatalyst-TiO2/C loading on the surface of the air (oxygen) electrode were introduced.In the case of the composite electrode,the current efficiency of electro-generated H2O2 is higher than 80%(J≤15mA/cm2).The degradation of aniline was used as an example to measure the influence of the composite electrode and compared with the system in which the air (oxygen) electrode and the photocatalyst-TiO2 were sqparated.The results confirmed that the composite electrode played an active role on accelerating the degradation rate of aniline.According to the measurement of the polarization curves of composite electrode and TiO2 photo anode,and of the adsorbing amount of aniline on the surface of the composite electrode,the principle of descending the recombination reta of photo-generated electron and hole and of enhancing the oxidation rate of organic molecule was described.The mechanism about the degradation of aniline was also discussed.
机译:介绍了产生氢气的空气(氧气)电极的制备方法以及在空气(氧气)电极表面负载光催化剂-TiO2 / C复合电极的方法。产生的H2O2高于80%(J≤15mA/ cm2)。以苯胺的降解为例来测量复合电极的影响,并与空气(氧气)电极和光催化剂TiO2的系统进行比较结果表明,复合电极对加速苯胺的降解速率起着积极的作用。根据复合电极和TiO2光阳极的极化曲线的测定以及苯胺在电极表面的吸附量的测定。描述了降低复合材料电极的光生电子与空穴的复合reta,提高有机分子氧化速率的原理。还讨论了苯胺的降解。

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