Large-scale synthesis of size-controllable Ag nanoparticles by reducing silver halide colloids with different sizes

摘要

In present study, double-jet precipitation method was employed to prepare the uniform AgX(X: Cl, Br, I)colloids, and then ascorbic acid/sodium borohydride was respectively used to reduce AgX into the silver nanoparticles(Ag NPs). The main experimental parameters about above two processes were investigated. It was found that under the same synthesis conditions the size of obtained Ag NPS was strongly dependent on the AgX size, and the silver particles obtained by reduction of AgCl, AgBr and AgI had the monotonously diminishing size order. SEM, TEM, XRD, and UV spectrometry were employed to characterize the obtained AgX and Ag NPs respectively, and they gave the size variation clearly and the mechanism was discussed.