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Synthesis, Structure and Transesterification of the Derivatives of b -Alkoxycarbonylethyltin Trichlorides with Diethyldithiocarbamate

机译:b-烷氧基羰基乙基锡三氯化物与二乙基二硫代氨基甲酸酯的衍生物的合成,结构和酯交换反应

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摘要

The derivatives of b -alkoxycarbonylethyltin trichlorides with diethyldithiocarbamate, ROCOCH2CH2Sn(S2CNEt2)Cl2, were synthesized and characterized by the means of elemental analysis, IR, 1H NMR and X-ray single crystal diffraction. The structural features of the compounds were described, and the possible mechanism of transesterification for compound 2a was suggested.
机译:合成了b-烷氧基羰基乙基锡三氯化物与二乙基二硫代氨基甲酸酯的衍生物ROCOCH2CH2Sn(S2CNEt2)Cl2,并通过元素分析,IR,1H NMR和X射线单晶衍射进行了表征。描述了化合物的结构特征,并提出了化合物2a酯交换的可能机理。

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  • 来源
    《中国化学快报(英文版)》 |2000年第6期|517-520|共4页
  • 作者

  • 作者单位

    Department of Chemistry, Qufu Normal University, Shandong, Qufu 273165;

    Department of Chemistry, Qufu Normal University, Shandong, Qufu 273165;

    Department of Chemistry, Qufu Normal University, Shandong, Qufu 273165;

    Department of Chemistry, Qufu Normal University, Shandong, Qufu 273165;

    State Key Laboratory Crystal Materials Shandong University, Shandong, Jinan 250100;

    State Key Laboratory Crystal Materials Shandong University, Shandong, Jinan 250100;

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  • 原文格式 PDF
  • 正文语种 chi
  • 中图分类 化学;
  • 关键词

    β-Aalkoxycarbonylethyltin trichloride; diethyldithiocarbamate; crystal structure; transesterification;

    机译:三氯化β-烷氧基羰基乙基锡;二乙基二硫代氨基甲酸酯;晶体结构;酯交换;
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