A Facile and Highly Stereoselective Reductive Debromination of Anhydro-6- (R)-Hydroxyethyl- 6-Bromopenicillin

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A Facile and Highly Stereoselective Reductive Debromination of Anhydro-6- (R)-Hydroxyethyl- 6-Bromopenicillin

机译：脱水-6-（R）-羟乙基-6-溴青霉素的简便且高度立体选择性还原脱溴

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Reductive debromination of anhydro-6-(R)-hydroxyethyl-6-bromopenicillin 7 by zinc in ammonium acetate gave 9 in 81% yield with high stereoselectivity of 6-(α):6-(β)=13:1.

机译：锌在乙酸铵中对脱水-6-（R）-羟乙基-6-溴青霉素7的脱溴脱溴反应得到9％的酯，收率为81％，立体选择性高，为6-（α）：6-（β）= 13：1。

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《中国化学快报（英文版）》 |2000年第5期|385-386|共2页
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Department of Chemistry, Zhejiang University, Hangzhou 310027;

Department of Chemistry, Zhejiang University, Hangzhou 310027;

Department of Chemistry, Zhejiang University, Hangzhou 310027;

Department of Chemistry, Zhejiang University, Hangzhou 310027;

Department of Chemistry, Zhejiang University, Hangzhou 310027;

National Laboratory of Applied Organic Chemistry,Lanzhou 730000;

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中图分类化学;
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Reductive debromination, stereoselectivity, anhydro-6-(R)-hydroxyethyl-6-bromo-penicillin;

机译：还原脱溴;立体选择性;脱水-6-（R）-羟乙基-6-溴青霉素;
入库时间 2022-08-19 04:03:27

A Facile and Highly Stereoselective Reductive Debromination of Anhydro-6- (R)-Hydroxyethyl- 6-Bromopenicillin

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