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Preparation and Electrochemical Properties of 3-Pyridinyl-6-aryl-1, 2, 4-triazolo 3, 4-b1, 3, 4thiadiazoles

机译:3-吡啶基-6-芳基-1,2,4-三唑3,4-b 1,3,4噻二唑的制备及电化学性质

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摘要

A series of 3-pyridinyl-6-aryl-1, 2, 4-triazolo[3, 4-b][1, 3, 4]thiadiazoles(PATT) were prepared, the structures were confirmed by IR and 1H NMR spectra. The results of cyclic voltammetry measurements imply that all these compounds have a higher electron affinity (EA)than 2-(4-biphenyl)-5-(4-tert-butyl phenyl)-1, 3, 4-oxadiazole (PBD) which implies that PATT could be acting as better electron acceptors than widely used electron transporting material PBD.
机译:制备了一系列3-吡啶基-6-芳基-1,2,4-三唑并[3,4-b] [1,3,4]噻二唑(PATT),结构经IR和1H NMR谱证实。循环伏安法测量的结果表明,所有这些化合物的电子亲和性(EA)比2-(4-联苯基)-5-(4-叔丁基苯基)-1,3,4-恶二唑(PBD)高,这意味着与广泛使用的电子传输材料PBD相比,PATT可以作为更好的电子受体。

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