The Studies of Rhodium-catalyzed Ring Opening Reaction of N-Boc-azabenzonorbornadiene with Heteroatom Nucleophiles

摘要

A rhodium-catalyzed ring opening reaction of N-Boc-azabenzonorbornadiene with heteroatom nucleophiles was described. Piperidine and piperazine’s derivatives were nucleo- philes in this reaction. The yields of the products 2a-f are good and the regioselectivity are excellent.