Novel Zn(Ⅱ) ladder-like coordination polymer constructed from designed ferrocenyl ligand

摘要

Reaction of Zn(NO_3)_2.6H_2O with 3-(4-carboxylphenylamino)-1-ferrocenyl-2-butylen-1-one (HL) and 4,4'-bipyridine (4,4'- bipy) in methanol solution resulted in a novel ladder-like coordination polymer {[Zn_2L_2(μ_2-L)_2(4,4'-bipy)_2].MeOH}_n (1).Its crystal structure,thermal and electrochemical properties are presented.