Electrochemical Study of FeCl₃ and FeCl₄- in BMImTf₂N-dimethylformamide Mixtures

摘要

Ionic liquids(ILs)as the solvent for electrochemical reaction are different from traditional molecular solvents such as dimethylformamide(DMF).Here we focus on the electrochemistry of FeCl3 and FeCl4-in BMImTf2N-DMF mixtures at different compositions.Firstly,we studied the electrochemistry of FeCl3in pure IL by ultramicroelectrode and observed two waves corresponding to the reduction of FeCl3,which