The first total synthesis of five linear diterpenes:eleganolone (1), eleganolone acetae (2),elegandiol (3), eleganonal (4) and epoxyeleganlone (5), was achieved from (E,E)-farnesol (6) via 4 to 6 steps. The key step was the alkylation reaction of silyl cyanide with allylic iodide.
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机译:Natural (天然) and units (高单位) nutrients (营养素) 13 one component (成分) Total (综合) Vitality (活力) Samtoh, high natural nutritious foods (食品) of the name is excellent (优秀) a domestic natural raw materials (国产自然原料) using 12 species (利用) and processing (加工处理) and a method of manufacturing (制造方法)