SYNTHESIS AND REACTIVITY OF OXOPEROXOMOLYBDENUM(Ⅵ)COMPLEXES:THE ACTIVE SPECIES IN THE HALCON EPOXIDATION PROCESS

摘要

Two oxoperoxomolytxlenum（Ⅵ）complexes,MoO（O₂）（OCH₂CH₂）₂NH.H₂O（5）andMoO（O₂）（OCH（CH₃）CH₂）₂ NH（6）have been synthesized by the reaction ofMoO₂（OCH₂CH₂）₂NH·CH₃OH（3）and MoO₂（OCH（CH₃）CH₂）₂NH（4）with tert-butyl hy-droperoxide,and are active to epoxidize cyclohexene.