CRYSTAL STRUCTURE AND SHG EFFECT OF COMPLEX Zn(POM)_2Br_2

摘要

[Zn（POM）2Br2]（POM is 3-Methyl-4-Nitropyridine-1-Oxide）,C12H12Br2N4O6Zn,Mr=533.44,triclinic,P1,a=11.450（3）,b=13.027（2）,c=6.605（1）,α=101.25（1）,β=96.96（2）,γ=108.06（2）°,V=901.2（4）3,Z=2,Dc=1.97g·cm-3,（MoKα）=0.71069,F（000）=520,μ=58.21cm-1,final R=0.040 for 2192 observed reflections,T=296K.The compound is amononuclear complex,containing a tetrahedrally coordinated zinc atom.