SVNTHESES AND CHARACTERIZATION OF TWO HIGH VALENCE VANADIUM COMPLEXES (?) SCHIFF-BASE LIGAND WITH RICH PHENOLATE OXVGEN AND THEIR CONVERSION

摘要

Two vanadium complexes of schiff base vith rich phenolate oxygen,o-()-salicylideneamino-methylphenol,had been synthesized and characterized.One is a V(Ⅳ)complex with an interaction viavanadyl oxygen and the other is a novel dinuclear V(V,V)complex with an oxo bridge.The conversionbetween the two complexes had been discussed.