Novel Properties of Supramolecular Complexes Formed by Pairing Cationic Porphyrin and Anionic Metal-Oxo Cluster

摘要

MTBPyP （me s o-tetrakis（4 -N- benzylpyridyl）porphyrin, M= H2, Zn） be aring positive charge has been shown to associate with SiW12O404- in water solution. The spectral evolution and Job’s plots analyses reveal that the relatively stable aggregates contain equal numbers of MTBPyP4+ and SiW12O404-