THE STUDY OF THE NON-STEADY KINETICS OF THE OXYDEHYDROGENATION OF ETHANE TO ETHYLENE OVER THE CATALYST OF Mo-V-Nb/Al_2O_3 BY THE TECHNIQUE OF TEMPERATURE PROGRAMMED TRANSIENT RESPONSE AND ELECTRIC CONDUCTIVITY

摘要

In this paper, instead of with the more expensive Fourier Transform Infrared Spectrometer（FTIR） a new technique of Temperature Programmed Transient Response（TP-TR） has been used with gas chromatography. Therefore, the TP-TR will be applied more widespreadly than ever before. With the technique of TP-TR and electric conductivity, the study is on the reaction mechanism and the adsorption behavior of the reactants and products to the present catalyst Mo-V-Nb/Al₂O₃ in the reaction from ethane through oxydehydrogenation to ethylene as the product. By Range-Kutta-Gill and Margarat methods, the kinetic parameters of the reaction elementary steps （i.e. rate constants, active energies and frequency factors） have been evaluated. The mathematical treatment coincides with the experimental results.