Efficient gaseous iodine capture enhanced by charge-induced effect of covalent organic frameworks with dense tertiary-amine nodes

摘要

Based on the outstanding application advantages of nitrogen-rich materials with regular porous frameworks in the capture of gaseous radioactive iodine,a series of covalent organic frameworks(COFs)with dual channels and abundant tertiary-amine active sites were constructed herein via a unique multinitrogen node design.The high density of up-to-six nitrogen adsorption sites in a single structural unit of the products effectively improved the adsorption capacities of the materials for iodine.Moreover,the adsorption affinity of the active sites can be further regulated by charge-induced effect of different electrondonating groups introduced into the COFs.Adsorption experiments combined with DFT theoretical calculations confirmed that the introduction of electron-donating groups can effectively increase the electron density around the active sites and enhance the binding energy between the materials and iodine,and thus improve the iodine adsorption capacity to 5.54 g/g.The construction strategy of multi-nitrogen node and charge-induced effect proposed in this study provides an important guidance for the study of the structure-activity relationship of functional materials and the design and preparation of high-performance iodine adsorption materials.