Isomorphous Substitution of Aluminium for Gallium in a Framework Gallophosphate

摘要

An aluminium-substituted framework gallophosphate with occluded triethylamine was synthesized hydrothermally. 27Al MAS NMR spectroscopy indicates that only the tetrahedral coordinated gallium atoms in the gallophosphate are substituted by aluminium atoms. The substitution leads to an evident decrease in cell volume of the crystal. The differences between the original gallophosphate and the aluminium-substituted one are also found for the IR spectrum and the thermal property.