5,10,15,20-Tetrakis(p-4-fluorobenzoyloxy)phenyl Porphyrin and Its Transition Metal Complexes

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5,10,15,20-Tetrakis(p-4-fluorobenzoyloxy)phenyl Porphyrin and Its Transition Metal Complexes

机译：5,10,15,20-四（对-4-氟苯甲酰氧基）苯基卟啉及其过渡金属配合物

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机译：The properties of porphyrins can be changed through the choice of peripheral substituents and inserted metal ions. To obtain porphyrin complexes with novel structures, 5,10,15,20-tetrakis(p-4-fluorobenzoyloxy) phenyl porphyrin(TFBOPPH2) and its transition metal complexes {TFBOPPM [M=Mn(Ⅲ), Fe(Ⅲ), Co(Ⅱ), Ni(Ⅱ), Cu(Ⅱ) and Zn(Ⅱ)]} were synthesized and characterized by means of UV-Vis, IR photoacoustic spectrometry, 1H NMR, elemental analyses, molar conductance, and XPS methods. A structure is proposed, in which one porphyrin molecule is coordinated with a transition metal ion in a tetradentate fashion, while the chlorine ion is the balanceable anion in Fe(Ⅲ) and Mn(Ⅲ) complexes.

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《高等学校化学研究（英文版）》 |2006年第4期|419-422|共4页
作者

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作者单位

College of Materials Science and Engineering Shandong University of Technology Zibo 255049 P. R. China;

College of Chemistry Jilin University Changchun 130023 P. R. China;

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收录信息中国科学引文数据库(CSCD);
原文格式 PDF
正文语种 chi
中图分类化学;
关键词
Porphyrin; Synthesis; Transition metal; Complex;

机译：卟啉;合成;过渡金属;复杂;

5,10,15,20-Tetrakis(p-4-fluorobenzoyloxy)phenyl Porphyrin and Its Transition Metal Complexes

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