Blends of Polypropylene and Syndiotactic 1,2-Polybutadiene:Morphology,Crystallization Behaviors and Mechanical Properties

摘要

Morphologies,crystallization behavior and mechanical properties of polypropylene(PP)/syndiotactic 1,2-polybutadiene(s-1,2 PB)blends were investigated.Morphology observation shows the well dispersed domains of s-1,2 PB in PP matrix with the rather small domain sizes from 0.1 to 0.5μm when the s-1,2 PB content increases from 5%to 20%(mass fraction)in the blends,and the phase structure tends to become co-continuous as s-1,2 PB content further increases.Crystallization temperature(Tc)of PP component in the blends is fluctuated with the variation of s-1,2 PB content in the blends.Compatibilization,to some extent,between the two components is inferred from the examination of both morphology and crystallization behavior.Improvement of impact strength of PP toughened by s-1,2 PB becomes significant only in the case of s-1,2 PB content above 20%(mass fraction).