Structure Evolution and Electrochemical Performance of Al_2O_3-coated LiNi_(0.4)Co_(0.2)Mn_(0.4)O_2 During Charge-discharge Cycling

摘要

Several lithium-ion batteries of 18650-type were assembled with pristine or Al2O3-coated LiNi0.4Co0.2Mn0.4O2(NCM) as cathode material and mesocarbon microbeads(MCMB) as anode material.The cycling performance of the batteries was examined under 25 °C at a 2C rate within a potential range of 2.75―4.20 V.The changes of the crystal structure,the lattice parameter,the mean crystallite size,and the mean micro-strain of pristine NCM and Al2O3-coated NCM during the charge-discharge cycling were determined by X-ray diffraction(XRD).The results indicate that the bulk structure of Al2O3-coated NCM is more stable than that of pristine NCM,which leads to the better cycling performance of Al2O3-coated NCM compared to that of pristine NCM.