利用循环流化床飞灰合成分子筛实验研究

摘要

Experimental study showed when n (SiO2) /n (Al2O3)≈3.3, Na2O/SiO2 was 1.2～1.5, H2O/Na2O was 40～70, the gel temperature was 60 -70 ℃, time continued 2h, reaction temperature was 90 -95 ℃, the crystallization time continued 4 -6 h, the fly ash of circulating fluidized bed boiler could synthesize the molecular sieve of higher crystallinity. It had better characteristic peak of P zeolite by the characterization of XRD, good stability by TGA. The relative degree of crystallization was 53%.%利用循环流化床锅炉粉煤灰在n(SiO2)/n(Al2O3)≈3.3、Na2O/SiO2为1.2～L 5、H2O/Na2O为40～70、凝胶温度和时间分别为60-70℃、时间2 h、晶化反应温度在90-95℃,晶化时间为4-6 h的条件下可以合成出较高结晶度的分子筛,通过XRD表征发现,产品具有良好的P型分子筛特征峰,其相对结晶度为53%.热重分析可知其具有好的稳定性.