The objective of this study was to examine the phosphorus (P) dynamics (changes in soil P either in quantity or form) and P movement under field and laboratory conditions as impacted by 33 years of beef cattle manure application at rates equivalent to one, two and three times the normal recommendation rates by Alberta Agriculture (1982), irrigation, and soil depth.;Concentration of sulphate ion (83.8 - 6313.9 mg SO4 2- L-1) and phosphate ions (0 to 7 mg L-1) in the leachate suggest possible anionic exclusion of phosphate ion from soil sorption sites with greater tendencies for the formation of calcium sulphate minerals in the soil and Ca-P-colloidal complexes in soil solution. Movement of these forms of P that is attached to Ca and colloidal particles is a possible mechanism responsible for P leaching observed in the groundwater. Generally, P concentration varies with depths and the greatest volume of soil solution was sampled at 120cm depth. Irrigation events in summer 2006 did not have any significant effect on solution P concentrations.;Sequential extraction of soil P suggests that the largest portion of P is associated with the NaHCO3 and HCl extractable fractions of soil P. The NaOH extractable P fraction remains relatively constant by the rate of manure application, suggesting the limited impact of Fe and Al as P-retaining cations in calcareous system.;Total extractable P (sum of P in the 5 extracts) increased with increasing rate of manure application at depths of 0 to 15 cm and significant impact of increasing rate of manure at 15 to 30 cm depth was only observed at rate of 120 Mg ha-1yr-1. Manure application significantly increased labile P fractions (form of P directly affecting P concentrations in soil solution) at all depth.;Leachate samples collected at depths of 30, 60 and 120 cm from the manured plots using suction cup lysimeters showed a range of concentrations of dissolved phosphorus which can have negative impact on surface and groundwater quality. Total P concentration in unfiltered soil leachate samples ranged between 0 to 7 mg L-1, with a mean concentration of 4 mg L-1. Molybate reactive P concentrations are generally less than 1 mg L-1 resulting in greater concentration of molybdate unreactive P. There is also a high possibility of P forms associated with colloidal particles contributing to the observed high concentration of molybate unreactive P apart from the recalcitrant organic forms of P.;The maximum, minimum and range of P concentrations observed in column leachates from soil samples at 0 to 15 and 15 to 30 cm layer increased with increasing rate of manure application. The inorganic P accounted for about 70 % of the P in the leachates. The maximum P concentrations were generally observed in these soils within the first 5 pore volumes, which is the same for both organic and inorganic forms of P. This confirmed that both organic and inorganic P forms are mobile.;Analysis of the impact of column leaching of the clay loam soil with 20 pore volumes of 0.01M CaCl2 indicate that the HCl fraction was a source of P while the NaHCO3 fraction was a sink for P during the column leaching process. This is confirmed by drastic reduction in HCl extractable P and an increase in NaHCO3 extractable P. This clearly indicates that the HCl fraction which has been classified as non-labile fraction significantly contributed to the P movement in this study.;The water, bicarbonate and HCl fractions are the major extractable P fractions responsible for the leachate P concentration, as positive and significant correlation was observed between these extractable P fractions and leachate P concentration. The highest rate of P movement was also observed at depth of 0 to 15 cm.;These studies confirmed that the rates of manure application over a long period of time should be of concern from environmental point of view as long term manure loading increased soil P content, and rate of release of P into soil solution at favorable hydrologic condition. Excessive loading of P will eventually leads to possible negative impact on soil and water quality.;Manure application in calcareous soil increased P forms associated with Ca. In the event of favorable hydrologic condition, the water, bicarbonate and HCl fractions, which constitute the largest fraction of extractable P, are the main P fractions that contribute to dissolved P in the soil. (Abstract shortened by UMI.)
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