Stress relaxation of comb polymers.

摘要

The goal of this work is to understand the rheological response of comb polymers in linear and nonlinear deformations. Model comb polymers with a moderate number (5-18) of short (marginally entangled to unentangled) branches and highly entangled backbones were examined in linear viscoelastic and nonlinear step strain flows. The hierarchical modes of relaxation were found to govern both the linear and nonlinear response. Appropriate modification of tube-model theory for entangled branches, inspired by recent work on asymmetric star polymers (where the short branch behaves as effectively larger on small timescales), provided a framework for quantitative predictions of the linear viscoelastic spectra. The extended nonlinear stress relaxation data over a wide time range (via time-temperature superposition) obeys time-strain separability and allows extraction of two damping functions, one for the branches at short times and one for the diluted backbone at long times. Both exhibit signatures of the comb architecture. The comb damping function at short times, shifted relative to the branch relaxation, is dominated by the retraction of branches and backbone end segments. The backbone damping function is rationalized by considering it as a linear chain that feels a smaller effective strain due to the prior branch relaxation.;We examine polybutadiene and polyisoprene combs in nonlinear shear flow to determine if convective constraint release (CCR) is an active relaxation mechanism for the comb architecture. CCR was recently proposed as an additional relaxation mechanism that only occurs at shear rates between the inverse of the longest relaxation time and the Rouse time of the comb backbone, t-1d,bbg&d2; t-1R,bb . We compare experimental data with a model incorporating CCR to provide evidence that CCR is a relaxation mechanism for the comb architecture.