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Crack resistance and strength properties of some alumina-based ceramics with tailored microstructures.

机译:一些具有定制微结构的氧化铝基陶瓷的抗裂性和强度性能。

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摘要

The microstructures of three different kinds of alumina-based ceramics, viz: (i) Coors AD85, (ii) alumina-anorthite, and (iii) alumina-aluminum titanate composites, have been tailored with the intent of altering their crack resistance (R- or T-curve) behavior. The influence of the two important microstructural parameters, viz: (i) internal residual stresses, and (ii) microstructural coarseness, on grain-localized crack bridging, a toughening mechanism responsible for the T-curve behavior in these materials in which intact grains exert frictional closure forces across the crack walls in the wake of an advancing crack tip, has been investigated. The residual stresses were tailored by crystallization of the intergranular glass, by quenching, and by the addition of a discrete second phase. The microstructural coarseness was tailored by homogeneous coarsening (scaling) and by heterogenous coarsening (incorporation of large grains within a fine-grain matrix).; In AD85 aluminas it has been shown that both crystallization of the intergranular glass and quenching have no effect on its flaw tolerance, a T-curve behavior derived mechanical property. On the other hand, in alumina-anorthite materials, crystallization of the intergranular anorthite glass resulted in a marked improvement in its flaw tolerance. Homogeneous microstructural coarsening of AD85 aluminas resulted in improved flaw tolerance, whereas the elongated nature of the grains in alumina-anorthite materials influenced its flaw tolerance only marginally. These results have been discussed with reference to the influence of the microstructural parameters on the bridging characteristics, in the light of an existing theoretical model.; It has been shown that addition of aluminum titanate to alumina results in improved flaw tolerance, whereas homogeneous coarsening of these microstructures results in a relatively weak material. However, heterogeneous microstructural coarsening resulted in composites with impressive flaw tolerance and T-curve properties. Direct evidence for active bridging in these composites has been presented. The processing of these tough ceramics has been discussed using a phenomenological model, and their mechanical properties have been discussed with reference to the influence of the microstructure on the bridging characteristics. A theoretical model describing bridging in heterogeneously coarsened (bimodal) microstructures has been presented.
机译:三种不同类型的氧化铝基陶瓷的微观结构经过了精心设计,旨在改变其抗裂性(R).Coors AD85,(ii)氧化铝-钙长石和(iii)氧化铝-钛酸铝复合材料。 -或T曲线)行为。两个重要的微观结构参数,即:(i)内部残余应力和(ii)微观结构粗糙度对晶粒局部裂纹桥接的影响,这是造成完整晶粒发挥作用的这些材料中T曲线行为的增韧机制。已经研究了在前进的裂纹尖端之后跨过裂纹壁的摩擦闭合力。通过晶间玻璃的结晶,淬火和添加离散的第二相来调整残余应力。微观结构的粗糙度通过均质的粗化(定标)和异质的粗化(在细晶粒基体中掺入大晶粒)来定制。在AD85氧化铝中,已经表明,晶界玻璃的结晶和淬火都对其缺陷耐受性没有影响,T曲线行为是由机械性能引起的。另一方面,在氧化铝-钙长石材料中,晶间钙长石玻璃的结晶导致其耐缺陷性显着提高。 AD85氧化铝的均质微观结构粗化可提高缺陷耐受性,而氧化铝-无烟煤材料中晶粒的拉长性质仅对其边缘耐受性产生很小的影响。根据现有的理论模型,已经参考微观结构参数对桥接特性的影响讨论了这些结果。已经表明,将钛酸铝添加到氧化铝中导致改善的耐缺陷性,而这些微观结构的均匀粗化导致相对较弱的材料。然而,非均质的微观结构粗化导致复合材料具有令人印象深刻的缺陷耐受性和T曲线特性。这些复合材料中主动桥联的直接证据已经提出。已经使用现象学模型讨论了这些坚韧陶瓷的加工过程,并参考微观结构对桥接特性的影响讨论了它们的机械性能。提出了描述异质粗化(双峰)微结构中桥接的理论模型。

著录项

  • 作者

    Padture, Nitin Prabhakar.;

  • 作者单位

    Lehigh University.;

  • 授予单位 Lehigh University.;
  • 学科 Engineering Materials Science.
  • 学位 Ph.D.
  • 年度 1991
  • 页码 184 p.
  • 总页数 184
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 工程材料学;
  • 关键词

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