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Use of zinc-lead alloy in galvanic stripping for iron removal.

机译:锌铅合金在电镀中用于去除铁。

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摘要

Due to the more and more stringent environmental regulations, the industrially generated residues and wastes consisting oxidized iron has become a serious problem to be dealt with. Researches to develop an effective, environmental friendly and economical process for solving this problem are enormously growing. Among these studies, galvanic stripping has eventually emerged as a promising, relatively inexpensive and highly efficient technique on the issue of iron removal.; The use of solid reductant, such as zinc or zinc-lead alloy, in organic reagent, D2EHPA in this study, to reduce iron in the organic to the ferrous state, which is loosely bonded to D2EHPA thus makes stripping no longer a problem, is the innovative part of this process. However, a variety of operation parameters, such as water content, oxygen concentration, reductant and its surface area, reductant surface modification, temperature, diluent, organic concentration, stripping solution, A/O ratio, separate and simultaneous stripping, can considerably affect the reaction rate and efficiency.; The primary objective of this study is investigating all these variables and therefore establishing a better and more complete optimization of the process control. Control mechanisms of the reaction and speculations to interpret various effects from different parameters are built possibly to have an in-depth understanding of the whole procedure. However, further research are continuously under study to confirm these speculations and more efforts are put in to establish this technique as an industrialized-ready process.
机译:由于越来越严格的环境法规,由氧化铁组成的工业产生的残留物和废物已成为一个严重的问题。开发有效,环境友好和经济的方法来解决该问题的研究正在迅速发展。在这些研究中,电镀脱皮最终成为一种有前途的,相对便宜且高效的除铁技术。在本研究中,在有机试剂D2EHPA中使用诸如锌或锌铅合金之类的固体还原剂,将有机态的铁还原为亚铁态,将铁松散地结合到D2EHPA上,从而使剥离不再成为问题。这个过程的创新部分。但是,多种操作参数(例如水含量,氧气浓度,还原剂及其表面积,还原剂表面改性,温度,稀释剂,有机物浓度,汽提溶液,A / O比例,单独和同时汽提)会极大地影响反应速率和效率。这项研究的主要目的是调查所有这些变量,从而建立更好,更完整的过程控制优化。建立反应的控制机制和推测以解释来自不同参数的各种影响的机制,可能会对整个过程有深入的了解。但是,正在继续进行进一步的研究以证实这些推测,并进行了更多的努力以将该技术确立为可工业化的过程。

著录项

  • 作者

    Chang, Chi-Ming.;

  • 作者单位

    University of Missouri - Rolla.;

  • 授予单位 University of Missouri - Rolla.;
  • 学科 Engineering Metallurgy.; Engineering Mining.
  • 学位 Ph.D.
  • 年度 1997
  • 页码 178 p.
  • 总页数 178
  • 原文格式 PDF
  • 正文语种 eng
  • 中图分类 冶金工业;矿业工程;
  • 关键词

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