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Degradation of glycol based aircraft deicing fluids under anaerobic methanogenic conditions.

机译:厌氧产甲烷条件下基于乙二醇的飞机除冰液的降解。

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Large quantities of aircraft deicing fluid (ADF) comprised mainly of ethylene glycol (EG) and propylene glycol (PG) are used for aircraft deicing/anti-icing during cold weather operations at airports throughout the world. Several different formulations of ADF have been developed and are used. Type I solutions are commonly employed to remove snow and ice from aircraft surfaces (deicing), and Type IV solutions are commonly applied to prevent ice from reforming (anti-icing).; The runoff from aircraft deicing operations is known to have a high oxygen demand. As a consequence, deicing wastes are often collected at airports for treatment. ADF products also contain small amounts of colorants, corrosion inhibitors, and thickeners, and these compounds may pose a greater environmental concern than oxygen depletion. Several studies have been completed to compare the relative toxicity of the pure glycols (EG and PG) vs. ADF using Microtox ® assays and other aquatic tests, and it has been reported that ADF is significantly more inhibitory than the pure glycols.; With growing concern over the environmental consequences of deicing there has been interest in developing anaerobic technology to treat deicing waste. In this dissertation a survey, a deicing waste characterization study, and research efforts employing serum bottles and bench scale laboratory reactors were used to demonstrate that ADF may be degraded effectively and efficiently in an anaerobic methanogenic environment. The factors that may affect this degradation are examined and discussed.
机译:在全球机场的寒冷天气运行期间,大量的主要由乙二醇(EG)和丙二醇(PG)组成的飞机除冰液(ADF)用于飞机除冰/除冰。已经开发并使用了几种不同的ADF配方。 I型溶液通常用于去除飞机表面的积雪和冰(除冰),IV型溶液通常用于防止冰再形成(防冰)。已知飞机除冰操作产生的径流对氧气的需求很高。结果,经常在机场收集除冰废物以进行处理。 ADF产品还包含少量的着色剂,缓蚀剂和增稠剂,与耗氧量相比,这些化合物对环境的影响更大。已经完成了一些研究,使用Microtox ®分析法和其他水生试验比较纯二醇(EG和PG)与ADF的相对毒性,据报道,ADF的抑制作用比纯乙二醇。随着对除冰的环境后果的日益关注,人们对开发用于处理除冰废物的厌氧技术感兴趣。在本文中,一项调查,一项除冰废物的表征研究以及使用血清瓶和台式实验室反应器的研究工作被用来证明ADF在厌氧产甲烷环境中可以被有效地降解。研究和讨论了可能影响这种降解的因素。

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