Dimensionless hydrodynamic simulation of high pressure multiphase reactors subject to foaming.

摘要

Safoniuk (1999) proposed that three-phase fluidized bed hydrodynamics can be scaled based on geometric similarity and matching of five dimensionless groups: the M-group, M = g(ρ_L − ρg)μ_L 4/(ρ_L2σ3); a modified Eötvös number, Eo* = g(ρ_L − ρ_g)d _p2/σ; the liquid Reynolds number, Re_L = ρ_Ld_pU_L/μ_L; a density ratio, ρ_p/ρ_L; and a superficial velocity ratio, U_g/U_L. Since many commercial reactors operate at high pressure with multicomponent liquids that may be subject to foaming, an experimental program was designed to test whether multiphase systems that match Safoniuk's criteria but differ in interfacial properties and gas density produce the same fluid dynamic parameters.; The liquid density, viscosity and surface tension were found to be insufficient to characterize bubble coalescence in multicomponent solutions. Multicomponent and contaminated liquids present interfacial effects that reduce the bubble coalescence rate and hinder the bubble rise velocity resulting in greater gas holdups than in pure monocomponent liquids under similar conditions. The extent of interfacial effects depends on the bubble size and is most important for Eo 40. Additional liquid physical properties such as dynamic surface tension and dilatational surface elasticity were also found insufficient since surface-active components were well-dispersed and in equilibrium with the gas-liquid interface. Gas density was found to be an important parameter in both gas-liquid and gas-liquid-solid systems. The dispersed bubble flow regime is sustained to higher gas velocities and gas holdups for denser gases.; As a secondary objective, a study on the role of particles in establishing radial uniformity of fluids that are initially maldistributed was undertaken in a 127 mm inner diameter column with 3.3-mm polymer particles and 3.7-mm glass beads (densities 1280 and 2510 kg/m3, respectively), with water and air as the liquid and gas. The effects of initial gas-liquid spatial maldistribution on overall phase holdups were not very significant for the glass beads since radial non-uniformities seemed to be eliminated relatively quickly.; Finally, the measurement of cross-sectional phase holdups using the attenuation and velocity change of ultrasound was attempted in a 292 mm inner diameter column with air, water and uniform glass beads of 1.3 mm diameter. The approach worked relatively well for gas-liquid and liquid-solid systems. However, signal attenuation greatly limits its use in three-phase fluidized beds, as it is difficult to operate at a frequency that ensures transmission through both dispersed phases. (Abstract shortened by UMI.)