Nonlinear finite element modeling of dental composite polymerization behavior.

摘要

Polymerization shrinkage has been one of the primary shortcomings preventing the use of resin composites as a universal dental restorative material. This shrinkage of the bonded restoration causes residual stresses in the composite which in turn are transferred to the adhesive interface. The deleterious effects of this stress environment include compromise of the interface itself and the decrease in the mechanical properties of the cured composite. Novel materials which claim to produce less shrinkage have been presented as a new class of restorative materials that could reduce the effects of this problem. One difficulty in assessing the actual in vivo benefits of these new materials is the fact that there is currently no direct way to measure the stress environment at the composite/tooth clinical interface. Computer modeling using finite element analysis (FEA) could provide helpful information regarding the clinical stress performance of dental composites. The purpose of this study was to develop a model that accurately simulates the nonlinear polymerization behavior of light-cured dental composites using a commercial FEA program, which could be accessible for future research.; Two phases were needed to accomplish this purpose. First, a data collection phase included volumetric shrinkage, shrinkage stress, tooth analog strain, and dynamic mechanical analysis experiments. Three composites, a standard methacrylate(Z250) and two experimental low stress epoxy-based composites (oxirane and silorane), were tested. The experimental results revealed an intriguing range of polymerization behavior exhibited by the three composites, indicating that the development of a low stress composite is possible. The information gathered from this phase supplied the necessary material input for the computer modeling, and provided empirical validation data for the model solutions. In the second modeling phase, an FEA approach based on a elastic/viscoplastic material model was used to develop models which included the nonlinear constitutive relationships involved in the polymerization behavior of the dental composites.; The approach was validated by modeling the curing behavior of the three different composites in the context of two different experiments. Good agreement between model and experimental values indicated that this approach was successful in simulating the polymerization behavior these composites.