Detailed fuel cell modeling for coal-based integrated gasification fuel cell system design and analysis.

摘要

Integrated gasification fuel cell (IGFC) systems that combine coal gasification and solid oxide fuel cells (SOFC) are promising for highly efficient and environmentally friendly utilization of coal for power production.;In this work, a dimensional finite volume model for planar SOFC has been developed for IGFC system design and analysis. The model can simulate SOFC overall performance and detailed internal profiles of species mole fractions, temperature, current density, and electrochemical losses. The model is capable of supporting recent SOFC improvements, including anode-supported design, the use of metallic interconnects, and reduced polarization losses. Sensitivity analysis is conducted to identify activation polarization parameters appropriate for modern SOFC modeling. The model is verified using literature available data and compared with state-of-the-art SOFC experimental data. Model results are shown for SOFC operation on humidified H2 and CH4-containing syngas, under co-, counter- or cross-flow configurations. The effects of fuel compositions and flow configurations on SOFC performance and thermal profiles are evaluated, and the implications of these results for system design and analysis are discussed.;Innovative IGFC designs are analyzed in Aspen PlusRTM first by employing a non-dimensional SOFC model. The sensitivity of IGFC thermal performance on the extent of carbon capture is also investigated. The most promising system identified consists of catalytic hydro-gasification, low-temperature gas cleaning, a hybrid fuel cell-gas turbine power block, and uniquely features recycling of the de-carbonized, humidified anode exhaust back to the hydro-gasifier. This system serves as a "baseline" case in the following work.;The developed dimensional SOFC model is linked with Aspen PlusRTM and employed for IGFC system analysis. The results further confirm the necessity of employing a dimensional SOFC model in IGFC design. To maintain the SOFC internal temperature within a safe operating range, the required cooling air flow rate is much larger than predicted by the non-dimensional SOFC model, which results in a large air compressor load and severely reduces the system efficiency. Options to mitigate the problem and improve IGFC performance are investigated and a design with staged SOFC stacks and cascading air flow can achieve a system efficiency of close to that of the baseline case.