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The Effect of Chemical Modification on Mechanical Properties of Carbon Black Filled Elastomer

机译:化学改性对炭黑填充弹性体力学性能的影响

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The aim of the work was to modify the acryloni-trile-butadiene rubber (NBR) in order to improve mechanical properties by enhancing filler-polymer interactions. Following compounds were used as the coupling agents: 2-isopropenyl-2-oxazoline (OKS), l-allyl-3-methylimidazo-lium chloride (AMC), l-vinyl-2-pyrrolidinone (NWP). Two types of carbon black were used as a reinforcing filler: pigment black FW200 and FEF N550. The fillers were characterized by dibutylphtalate (DBP) absorption analysis, aggregates size, rheological properties of filler suspensions and zeta potential analysis. The compounding was carried out in a laboratory rolling mill. Samples were prepared through the vulcanization process at 160°C. The vulcanization kinetics of rubber compounds, crosslink density and mechanical properties of vulcanizates were also measured.
机译:这项工作的目的是对丙烯腈-丁苯橡胶(NBR)进行改性,以便通过增强填料-聚合物的相互作用来改善机械性能。下列化合物用作偶联剂:2-异丙烯基-2-恶唑啉(OKS),1-烯丙基-3-甲基咪唑鎓氯化物(AMC),1-乙烯基-2-吡咯烷酮(NWP)。两种类型的炭黑用作增强填料:颜料黑FW200和FEF N550。通过邻苯二甲酸二丁酯(DBP)吸收分析,聚集体尺寸,填料悬浮液的流变性质和Zeta电位分析来表征填料。配混在实验室轧机中进行。通过在160℃的硫化过程制备样品。还测量了橡胶混合物的硫化动力学,交联密度和硫化橡胶的机械性能。

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