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INtercalation of SOdium-Potassium ALloys into Graphite

机译:钠钾合金插入石墨中

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The intercalation, at room temperature, of the sodium-potassium eutectic into graphite is performaed ,in a glove box under purified argon. It leads ot a high alkali metal ocntent powder. The annealing under vacuum, at 200 deg C for two days leads to a pure first stage compound whose formula is NaK_2C_12 with a color and a structure close to that of KC_8. This phase is unstable and decomposes slowly in a mixture of KC_8 and free alloy. However, this free alloy, which is liquid at room temeprature, remains as inclusions between the graphene layers and the compound remains as a powder which can be useful for some applications when one needs large quantities of an alkali metal"solid" at room temperature, e.g. for gas purification, for rapid and intense heat provider, for ionic polymerization catalyst...
机译:在纯氩气的手套箱中,在室温下将钠钾共晶体嵌入石墨中。它会导致产生高碱金属含量的粉末。在真空中于200℃退火两天,得到纯的第一步化合物,其分子式为NaK_2C_12,其颜色和结构接近KC_8。该相不稳定,并在KC_8和游离合金的混合物中缓慢分解。但是,这种在室温下为液态的游离合金保留为石墨烯层之间的夹杂物,而该化合物则以粉末形式保留,当人们在室温下需要大量碱金属“固体”时,这些粉末可用于某些应用。例如用于气体净化,用于快速提供大量热量,用于离子聚合催化剂...

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