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COMPATIBILIZATION OF ABS/PA6 BLENDS USING OLEFIN BASED POLYMERS

机译:使用基于烯烃的聚合物对ABS / PA6混合物的相容性

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摘要

This study focuses on the morphologies, mechanical and thermal properties of poly(acrylonitrile-co-styrene-graft-butadiene)/polyamide-6 (ABS/PA6) blends compatibilized with methyl acrylate and glycidyl methacrylate grafted polyethylene (E-MA-GMA) and n-butyl acrylate and maleic anhydride grafted, carbon monoxide modified polyethylene (E-nBA-MAH). The ABS/PA6 ratio (100:0, 80:20, 50:50, 20:80 and 0:100) and compatibilizer content (0, 5 and 10%) are examined as the experimental variables. Compatibilization improves impact strength of the blends. Super-tough blends were obtained at definite compositions (ABS/PA6/E-nBA-MAH: 50/50/5, ABS/PA6/E-MA-GMA: 50/50/5). Dispersed domain size became remarkably smaller for compatibilized blends compared to incompatibilized ones. It was concluded that olefin based copolymers are potential compatibilizers for ABS/PA6 blends.
机译:这项研究的重点是与丙烯酸甲酯和甲基丙烯酸缩水甘油酯接枝的聚乙烯(E-MA-GMA)相容的聚(丙烯腈-共苯乙烯-接枝-丁二烯)/聚酰胺6(ABS / PA6)共混物的形态,力学和热性能丙烯酸正丁酯和马来酸酐接枝的一氧化碳改性聚乙烯(E-nBA-MAH)。检查ABS / PA6的比例(100:0、80:20、50:50、20:80和0:100)和增容剂含量(0、5%和10%)作为实验变量。相容性提高了共混物的冲击强度。以一定的组成(ABS / PA6 / E-nBA-MAH:50/50/5,ABS / PA6 / E-MA-GMA:50/50/5)获得超韧共混物。与不相容的混合物相比,相容的混合物的分散域尺寸明显变小。结论是,烯烃基共聚物是ABS / PA6共混物的潜在增容剂。

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