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Study on Light Degradation of 2,4-dichlorophenol in Wastewater by Using Excimer UV Source

机译:准分子紫外光源光降解废水中2,4-二氯苯酚的研究

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摘要

A study on degradation of 2,4-dichlorophenol in aqueous solution using 172nm excimer UV source is reported. Degradation products were analyzed by Gas chromatography time-of-flight mass spectrometry. The experiment results show that a low concentration (1mg/L) and a high concentration (10mg/L) of 2,4-dichlorophenol are directly irradiated separately. By GC-TOFMS technique analysis, the results indicate that under the irradiation the 1mg/L of 2,4-dichlorophenol is extremely unstable and decompose completely in 1.5 minutes. However, after 10 minutes irradiation on the 10 mg/L of 2,4-dichlorophenol, the degradation products of 2-chlorophenol, phenol, benzenediol and benzoquinone are detected. The possible process of the degradation of 2,4-dichlorophenol by excimer UV resource is presented.
机译:报道了使用172nm准分子紫外光源降解水溶液中2,4-二氯苯酚的研究。通过气相色谱飞行时间质谱法分析降解产物。实验结果表明,分别直接辐照低浓度(1mg / L)和高浓度(10mg / L)的2,4-二氯苯酚。通过GC-TOFMS技术分析,结果表明,在辐射下1mg / L的2,4-二氯苯酚极不稳定,并在1.5分钟内完全分解。但是,在10 mg / L的2,4-二氯苯酚上照射10分钟后,检测到2-氯苯酚,苯酚,苯二醇和苯醌的降解产物。提出了准分子紫外光资源降解2,4-二氯苯酚的可能过程。

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  • 来源
  • 会议地点 Beijing(CN)
  • 作者单位

    LIU Tiebing@Shanghai Applied Radiation Institute, Shanghai University, Shanghai 201800, China;

    National Centre of Agricultural Standardization and Inspection (Anhui), Hefei 230051, Anhui, China--WU Minghong@Shanghai Applied Radiation Institute, Shanghai University, Shanghai 201800, China--DI Yan@Structure Research Laboratory, University of Science and Technology of China, Hefei 230026, Anhui, China--LI Zhen@Shanghai Applied Radiation Institute, Shanghai University, Shanghai 201800, China--LI Qianrong@Structure Research Laboratory, University of Science and Technology of China, Hefei 230026, Anhui, China--YIN Hao@Structure Research Laboratory, University of Science and Technology of China, Hefei 230026, Anhui, China--SHI Wenyan@Shanghai Applied Radiation Institute, Shanghai University, Shang;

  • 会议组织
  • 原文格式 PDF
  • 正文语种
  • 中图分类 环境科学基础理论;
  • 关键词

    excimer UV source; degradation; 2,4-dichlorophenol;

    机译:准分子紫外线源;降解; 2,4-二氯苯酚;

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