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Mesozoic gold deposits in the Shandong Peninsula, P. R. China

机译:中国山东半岛中生代金矿床

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The Jiaodong Peninsula of Shandong Province is located in the east portion of the North China Craton and is the largest district of gold mining and production in China. The Peninsula possesses over 25% of China's total exploited gold reserves and currently provides more than one fourth of China's total gold production per annum. The basement of the Jiaodong Peninsula consists of Archean - Proterozoic metamorphosed rocks, mainly amphibolite, granulite, gneiss, schist, marble, quartzite and sandstone. The rocks were subjected to multiple stages of granulite - to greenschist - facies metamorphism during the timespan 2945~1674 Ma. The basement was reactivated by the Mesozoic Yanshanian orogeny (Jurassic to Cretaceous), which was an important tectono - magmatic - mineralization event in the area. The Early Yanshanian (130 to 160 Ma) granitoids were formed by anatexis of the basement rocks. More than 80% of the lode gold deposits in the Peninsula are hosted within the granitoids and/or along the contact zones between the granitic and basement rocks, and together constitute the largest granitoid - related gold province in the world. Two types of gold deposits are recognised: (1) lode gold - quartz - sulphide veins (i. e., the Linglong type); and (2) shear - zone hosted disseminated sulphides (i. e., the Jiaojia type). Both types of gold deposits are similar in their geology and geochemistry. Ore mineral assemblages are dominated by pyrite, followed by galena, sphalerite, chalcopyrite, pyrrho-tite and arsenopyrite. Gold - silver - bearing minerals are mainly composed of native gold and electrum. Four stages of mineralization include (1) pyrite-quartz, (2) gold - bearing pyrite - quartz, (3) gold - bearing multiple metallic sulphides and quartz and (4) quartz - carbonate. The gold is concentrated in stages 2-3. Alteration minerals consist of sericite, mus-covite, sulphides (mainly pyrite, pyrrhotite and arsenopyrite), carbonates, K - feldspar, chlorite, and kaolinite. Radiogenic ages of mineralization, dated by Rb - Sr and K - Ar methods on hydrothermal and ore minerals and inclusion fluids, are mostly between 100 ± 4 to 135 ± 5 Ma for eight major gold deposits. These ages are 5 to 20 million years less than those of corresponding host granitic intrusions in the main ore belt. Mineralizing fluids are H_2O - CO_2 - NaCl solutions (salinity: < 12 wt.% NaCl equiv.) at minimum T- P of 250—350℃ and 0.3~1 kbar. Isotopic compositions of ore minerals or inclusion fluids are: δ~(13)C (0 to -5 per thousand), δ~(34)S (+4 to + 12 per thousand), δD and δ~(18)O (-20 to-110 per thousand; -10 to +8 per thousand). On the basis of the geological, geochemical and isotopic data, it is suggested that the gold mineralization in the Jiaodong Peninsula post - dated the granitic emplacement and was formed mainly by evolved meteoric waters in the waning stages of the Mesozoic Yanshanian orogeny at c. 100 to 130 Ma.
机译:山东省胶东半岛位于华北克拉通的东部,是中国最大的金矿开采和生产区。半岛拥有中国开采黄金总储量的25%以上,目前每年提供的黄金占中国黄金总产量的四分之一以上。胶东半岛的地下室由太古代-元古代变质岩组成,主要是角闪石,花岗石,片麻岩,片岩,大理石,石英岩和砂岩。在2945〜1674 Ma的时间段内,岩石经历了多阶段的花岗质-绿岩-相变质作用。中生代燕山期造山运动(侏罗纪至白垩纪)使基底重新活化,这是该地区重要的构造-岩浆-成矿事件。燕山期早期(130至160 Ma)花岗岩体是由基底岩石的后突形成的。半岛80%以上的金矿床都位于花岗岩内部和/或花岗岩与基底岩石之间的接触区域,共同构成了世界上最大的与花岗岩相关的金矿。可以识别出两种类型的金矿床:(1)矿床金-石英-硫化物矿脉(即灵龙型); (2)剪切带上散布着的硫化物(即焦家型)。两种类型的金矿床在地质和地球化学上都相似。矿石矿物组合以黄铁矿为主,其次是方铅矿,闪锌矿,黄铜矿,黄铁矿和毒砂。含金-银的矿物主要由天然金和电子组成。成矿的四个阶段包括(1)黄铁矿-石英,(2)含金的黄铁矿-石英,(3)含金的多种金属硫化物和石英以及(4)石英-碳酸盐。黄金集中在2-3阶段。蚀变矿物包括绢云母,白云母,硫化物(主要是黄铁矿,黄铁矿和毒砂),碳酸盐,钾长石,绿泥石和高岭石。 Rb-Sr和K-Ar方法对热液,矿石矿物和包裹体流体的成矿成矿年龄主要在8个主要金矿床之间,在100±4至135±5 Ma之间。这些年龄比主矿带中相应的主花岗岩侵入年龄要短5至2000万年。矿化流体为H_2O-CO_2-NaCl溶液(盐度:<12 wt。%NaCl当量),最小T-P为250-350℃,压力为0.3〜1 kbar。矿石矿物或包裹体流体的同位素组成为:δ〜(13)C(千分之0至-5),δ〜(34)S(千分之4至+12),δD和δ〜(18)O( -20至-110 /千; -10至+ 8 /千。根据地质,地球化学和同位素数据,表明胶东半岛的金矿化早于花岗质沉积,主要是由中生代燕山期造山运动在c的衰落阶段形成的陨石水形成的。 100至130 Ma。

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