Synthesis and Characterization of Delafossite CuLaO_2 for Thermoelectric Application

摘要

The preparation of single-phase CuLaO_2 with delafossite-type structure by means of the solid-state reaction method was investigated using X-ray diffraction. The results showed that notwhistanding the fact that there was a trace of metallic copper, nearly single-phase CuLaO_2 was obtained by using La(OH)_3 as a lanthanum source and by firing the mixed powder with nonstoichiometric composition ratio of La(OH)_3:Cu_2O =1:1.425 in a vacuum at 1273 K for 10 h. The measurement of electrical conductivity and Seebeck coefficient showed that CuLaO_2 thus obtained was a p-type semiconductor and had a Seebeck coefficient of approximately 70 μV/K.