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Electrochromic oxides: microstructures and optical properties

机译:电致变色氧化物:微观结构和光学性质

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Abstract: This paper attempts to lay down a foundation for a comprehensive theory of electrochromism among oxides. It is pointed out that crystals of all the well known electrochromic metal (Me) oxides are composed of MeO$-6$/ octahedra in various corner-sharing and edge-sharing arrangements. In electrochromic thin films there are cluster-type and columnar microstructures based on the MeO$-6$/ units. The coordination of the ions leads to schematic electronic bandstructures that, at least for the (defect) perovskite and rutile lattices, are able to explain the presence or absence of cathodic and anodic electrochromism. Small polaron absorption prevails in disordered oxides.!44
机译:摘要:本文试图为氧化物间电致变色的综合理论奠定基础。要指出的是,所有众所周知的电致变色金属(Me)氧化物的晶体均由MeO $ -6 $ /八面体以各种角共享和边缘共享的方式组成。在电致变色薄膜中,有基于MeO $ -6 $ /单位的簇状和柱状微结构。离子的配位导致示意性的电子能带结构,至少对于(缺陷)钙钛矿和金红石晶格,它们能够解释阴极和阳极电致变色的存在与否。小的极化子吸收主要存在于无序的氧化物中!44

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