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Alkaline/Surfactant Flood Potential in Western Canadian Heavy Oil Reservoirs

机译:西加拿大重油箱中的碱/表面活性剂泛潜力

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For heavy oil reservoirs (with oil viscosities ranging from 1,000 to more than 10,000 mPa.s), primary production and waterflood can only recover 5 to 10% initial oil-in-place (IOIP) due to the unfavourable mobility ratio of the water phase to the oil phase. Heavy oils usually have a relatively high content of organic acids, which can be neutralized by alkalis to form in-situ surfactants. With the assistance of these in-situ surfactants, an oil-in-water emulsion with a much lower viscosity than heavy oil can be generated. In this way, the heavy oil is entrained in the water phase and produced out of the reservoir. An initial study was carried out to evaluate the feasibility of alkaline/surfactant (A/S) flooding for western Canadian heavy oil reservoirs. The integrated approach included extensive emulsification tests, oil/brine interfacial tension measurements, viscosity measurements, and sandpack flood tests. The experimental results showed that the dynamic interfacial tension of oil/water can be lowered to an ultralow level (< 0.01 dyne/cm) by an alkaline solution and a very dilute concentration of surfactant, leading to easy emulsification of heavy oil in formation brine under slight interfacial disturbance. A series of sandpack flood tests were carried out to investigate the recovery performance of A/S flooding for five western Canadian heavy oils with viscosities ranging from 650 to 18,000 mPa.s at 22°C. Tertiary oil recoveries in sandpack flood tests were between 20 to 30% IOIP. The results of these sandpack flood tests suggest that A/S flooding is a promising enhanced oil recovery process for thin heavy oil reservoirs, in which thermal processes are not suitable.
机译:对于重油储层(具有1,000至超过10,000MPa的石油粘度),由于水相的不利迁移率,初级生产和水运量只能恢复5至10%的初始油状物(IOIP)对油阶段。重油通常具有相对高的有机酸含量,其可以通过碱中和以形成原位表面活性剂。通过这些原位表面活性剂的辅助,可以产生具有比重油更低的粘度低得多的水乳液。以这种方式,重油被夹带在水相中并从储存器中产生。进行了初步研究以评估西加拿大重油储层碱/表面活性剂(A / S)洪水的可行性。综合方法包括广泛的乳化试验,油/盐水界面张力测量,粘度测量和砂包洪水试验。实验结果表明,通过碱性溶液和非常稀释的表面活性剂,可以将油/水的动态界面张力降低到超级水平(<0.01达因/厘米),从而易于在形成盐水中易于乳化重油轻微的界面障碍。进行了一系列Sandpack洪水试验,以研究A / S洪水对五个加拿大重油的恢复性能,粘度范围为650至18,000MPa。22°C。 Sandpack洪水试验中的第三次油回收率在20至30%的IoIP之间。这些Sandpack洪水试验的结果表明,A / S洪水是薄重油储层的有希望的增强的采油过程,其中热过程不合适。

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