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Experimental and Computational Studies on Underground Gasification of Turkish Lignite

机译:土耳其褐煤地下气化的实验与计算研究

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Underground coal gasification (UCG) is more advantageous than conventional coal combustion processes, as the first requires lower investment/ handling costs and operates environmentally friendly. Lignite is of utmost importance for the Turkish economy as Turkey has ~15 billion tons of lignite reserves. In this work, we have performed ex-situ reactor experiments to explore the gasification ability of Turkish lignite and to simulate and characterize the UCG process. Preliminary coal gasification tests were carried out with oxygen and steam for Malkara Pirinccesme (Turkey) lignite, which is characterized by high ash contents and low moisture. During the gasification experiments, temperature distribution inside the coal seams was monitored and the syngas outflow rate was measured. Additionally, syngas compositions were analysed using an MRU Varioplus Syngas analyser and an Agilent 7890B gas chromatograph. Results represent that the Turkish lignite sources are suitable for gasification. Experiments were divided into several phase: 1) oxygen phase 2) air- oxygen mixture phase, 3) steam-oxygen mixture phase, 4) air-oxygen-steam mixture phase, The syngas produced in the oxygen gasification stage was characterized by high calorific values of 6-9 MJ/Nm~3, carbon monoxide contents of 23-33 vol.%, and hydrogen contents of 20-30 vol.%. Also, computational models of the experimental setup was built and simulations were performed in ANSYS Fluent to elucidate the optimal parameters required for the high calorific syngas production; such as gasification agent rates, shape of the gasification channel, etc.
机译:地下煤气化(UCG)比传统的煤炭燃烧过程更有利,因为第一个需要降低投资/处理成本并运行环保。 Lignite对土耳其经济至关重要,因为土耳其拥有〜150亿吨褐煤储备。在这项工作中,我们已经进行了前地反应堆实验,以探讨土耳其褐煤的气化能力,并模拟和表征UCG过程。用氧气和蒸汽进行初步煤气化试验,用于Malkara Pirinccesme(土耳其)褐煤,其特征在于高灰分含量和低水分。在气化实验期间,监测煤层内的温度分布,并测量合成气流出速率。另外,使用MRU Varioplus合成气分析仪和Agilent 7890b气相色谱仪进行分析合成气组合物。结果表示土耳其褐煤来源适用于气化。实验分为几相:1)氧相2)空气 - 氧混合物相,3)蒸汽 - 氧混合相,4)空气 - 氧气混合物相,在氧气化阶段生产的合成气以高热量为特征值6-9 mJ / nm〜3,一氧化碳含量为23-33体积%,氢气含量为20-30体积%。%。此外,建立了实验设置的计算模型,并在口碑流利地进行了模拟,以阐明高热合成气生产所需的最佳参数;如气化剂速率,气化通道的形状等

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