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Magnetic Nanoparticle Supported Phosphotungstic Acid: An Efficient Catalyst for the Synthesis of Xanthene Derivatives

机译:磁性纳米颗粒支持磷钨酸:合成X吨衍生物的有效催化剂

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Magnetic nanoparticle supported phosphotungstic acid (Fe_3O_4@SiO_2-HPW) was applied as a highly efficient catalyst for the synthesis of 14H-dibenzoxanthene derivatives via condensation reaction of 2-naphthol and aryl aldehydes. The catalyst was found highly efficient for the synthesis of xanthene derivatives under solvent free condition. The catalyst showed high activity and stability during the reaction and provided excellent yield of the corresponding products in short reaction time. All the synthesized compounds were characterized through FT-IR, ~1H-NMR and ~(13)C-NMR spectroscopic techniques. Furthermore, the catalyst is magnetically recoverable and can be reused several times without significant loss of its catalytic activity.
机译:将磁性纳米粒子负载磷酸锰酸(Fe_3O_4 / 2-HPW)作为高效催化剂,用于通过2-萘酚和芳基醛的缩合反应合成14H-二苯并氧蒽衍生物。 在无溶剂条件下,发现催化剂高效合成X吨衍生物。 催化剂在反应过程中显示出高活性和稳定性,并在短反应时间内提供相应产物的优异产率。 通过FT-IR,〜1H-NMR和〜(13)C-NMR光谱技术表征所有合成的化合物。 此外,催化剂是磁性可回收的,并且可以重复使用几次,而不会显着损失其催化活性。

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