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Formaldehyde-free urea granules

机译:无甲醛尿素颗粒

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Urea formaldehyde is the currently state of the art urea granulation additive. Its use is absolutely crucial in order to achieve the required product quality such as crushing strength, bulk density or low caking tendency. Furthermore it is also an inherent granulation aid which ensures a proper performance of the granulation process itself by limiting the generation of dust and providing a high build up rate of the granules. Unfortunately there are also some negative aspects to the use of the pre-condensates of formaldehyde and urea (UF 80, UF85). A major disadvantage is that it still contains a considerable amount of free formaldehyde which is harmful to health. It is categorized as a carcinogenic substance by the IARC (International Agency for Research on Cancer). In addition to that UF solutions contain a certain amount of methanol. Hence, it contributes to a significant part to the VOC emissions from an ammonia/urea complex, which might be requested to be very low by the local authorities. Furthermore urea product treated with formaldehyde cannot be sold as technical grade for most applications. It is not within the specification for the preparation of DEF (Diesel Exhaust Fuel) also known as AdBlue~R. It was UFTs goal in the past years to develop an alternative additive which is capable to guarantee the same product quality as well as at least the same process performance parameters while not contributing to any environmental impact. The result of the development is an alternative additive, which shows a product quality and a granulation performance which is at least as good as the bench mark UF. Different from UF solutions it is not harmful to health or the environment, since it consists of components which are biodegradable and are allowed to come into contact with food. Additionally the application of the alternative additive bears the possibility of utilizing the same urea granules for fertilizer, technical and DEF applications. This extends the range of application of urea ganules and reduces the efforts with regard to logistics for all producers of multiple urea grades drastically.
机译:尿素甲醛是目前现有技术的尿素造粒添加剂。其使用绝对是至关重要的,以实现所需的产品质量,例如破碎强度,散装密度或低结块趋势。此外,它也是一种固有的造粒助剂,其通过限制灰尘的产生并提供颗粒的高积聚速率来确保造粒过程本身的适当性能。遗憾的是,使用甲醛和尿素的预缩合(UF 80,UF85)也存在一些消极的方面。主要缺点是它仍然含有相当多的游离甲醛,这是对健康有害的。它被IARC(癌症研究的国际机构)分为致癌物质。除了UF溶液含有一定量的甲醇。因此,它有助于来自氨/尿素复合物的VOC排放的重要组成部分,这可能被地方当局要求非常低。此外,用甲醛处理的尿素产物不能为大多数应用的技术级出售。它不在制备DEF(柴油排气燃料)的规范内,也称为Adblue〜R。这是过去几年的UFTS目标,开发一种替代添加剂,该替代添加剂能够保证相同的产品质量以及至少相同的过程性能参数,同时不会导致任何环境影响。开发的结果是替代添加剂,其显示产品质量和造粒性能,至少与台式标记UF一样好。与UF解决方案不同,它对健康或环境没有危害,因为它由可生物降解的组件组成,并且被允许与食物接触。另外,替代添加剂的应用耐受利用相同的尿素颗粒用于肥料,技术和DEC应用。这延长了尿素流量的应用范围,并减少了对所有多种尿素级的所有生产者的物流急剧上的物流的努力。

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