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Characterization of Various Size ZnO Nanorods Prepared by RF Sputtering and Hydrothermal Method

机译:RF溅射制备的各种ZnO纳米棒的表征及水热法

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In this paper, we used RF sputter to deposit the ZnO seed layer of 0.6 μm in thickness, which was then immersed in zinc nitrate hexahydrate [Zn(NO_3)_2·6H_2O] and hexamethylenetetramine (C_6H_(12)N_4) mixture solution of different concentrations for the growth of ZnO nanorods by hydrothermal method. After annealing at different temperatures, thermal field emission scanning electron microscope (TFSEM) was used to observe the arrangement and growth of ZnO nanorods. We found the concentration of the mixture solution of C_6H_(12)N_4 and Zn(NO_3)_2·6H_2O would affect the thickness and crystallization of ZnO nanorods, and the annealing temperature would change their columnar arrangement structure. The arrangement structure of the ZnO nanorods grown in the mixture solution of 0.2 M concentration had more gaps and pores. Under this condition, we successfully fabricated a dye-sensitized solar cell (DSSC), of which the performance could be further improved by using ZnO nanorods prepared by many different methods.
机译:在本文中,我们使用RF溅射将ZnO种子层沉积厚度为0.6μm,然后将其浸入硝酸锌六水合物[Zn(NO_3)_2·6H_2O]和六亚甲基甲酰胺(C_6H_(12)N_4)混合物溶液中的不同水热法生长ZnO纳米棒的浓度。在不同温度下退火后,使用热场发射扫描电子显微镜(TFSEM)来观察ZnO纳米棒的排列和生长。我们发现C_6H_(12)N_4和Zn(NO_3)_2·6H_2O的混合物溶液的浓度会影响ZnO纳米棒的厚度和结晶,并且退火温度会改变其柱状布置结构。在0.2M浓度的混合物溶液中生长的ZnO纳米棒的布置结构具有更多的间隙和孔隙。在这种情况下,我们成功地制造了一种染料敏化的太阳能电池(DSSC),其中通过使用许多不同方法制备的ZnO纳米棒可以进一步改善性能。

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