LOW-TEMPERATURECATALYTIC CLEARING OF GASES OF THERMAL POWER STATION FROM HARMFUL IMPURITY IN THE PRESENCE OF THE COBALT COMPLEXES FIXED ON A POLYMERIC MATRIX

摘要

The results of optimization of catalysts for gases clearing from sulfur dioxide using processes of oxidation are presented in this work. The researches carried out with the help of modern methods: kinetic, IR-, UV- spectrophotometric, viscometry, LG-chromatography, redox-potentiometric. It is shown, that developed complexes of transitive metals immobilized on a polymeric matrix are highly effective and stable catalysts for the sulphur dioxide oxidation processes. By the example of cobalt compounds the reactions kinetic investigated in details, the kinetic equation is received, allowing to optimize process of gases clearing from sulfur dioxide, kinetic and thermodynamic parameters of process are calculated.