Emissions from Residential Wood Pellet Boilers and Stove Characterized into Start-up, Steady Operation, and Stop Emissions

摘要

Gaseous and particulate emissions from three residential wood pellet boilers and a stove were characterized and quantified at start-up, steady (full, medium and low combustion, power), and stop phases. The aim was to characterize the emissions during the different phases of boiler operation and to identify when the major part of the emissions occur to enable actions for emission reduction where the savings can be highest. The investigated emissions comprised carbon monoxide (CO), nitrogen oxide (NO), total organic carbon (TOC), and particulate matter (PM 2.5). In this study, particle emissions were characterized by both number and mass concentration. The emission characteristics at high combustion power were relatively similar for all tested devices while significant differences in CO and TOC were observed at lower combustion power. Highest CO and TOC emissions are produced by the bottom fed boiler at low combustion power. The accumulated start-up emissions of the tested devices varied in the ranges of 0.5-12 g CO, 0.1-0.7 g NO, 0.1-2 g TOC, 0.12-2,9 g PM2.5, and 2,4 X 10~(13) to 3.1 X 10~(14) particles PM2.5. The accumulated stop emissions varied in the ranges 4-15.5 g CO, 0.01-0.11 g NO, 0.02-1.6 g TOC, 0.1-1.3 g PM2.5, and 3.3 X 10~(13) to 1.4 X 10~(14) particles PM2.5. The bottom fed boiler Bl had higher start-up and stop emissions than the tested top fed boilers and more particle emissions were accumulated in start-up phase than in stop phases of boiler Bl, B3, and stove SI. Number of particles emitted from residential wood pellet combustion is dominated by fine particles smaller than 1 μm and similar particle distribution both in number and mass were observed for the tested devices. The start-up phase generated higher accumulated particle mass than the stop phase.