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FAILURE OF THE MAXWELL RELATION FOR THE QUANTIFICATION OF CALORIC EFFECTS IN FERROIC MATERIALS

机译:麦克斯韦尔关系失败,以便在铁野材料中量化热量效应

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Giant caloric effects were reported in elasto-, electro- and magnetocaloric materials near phase transformations. Commonly, their entropy change is indirectly evaluated by a Maxwell relation. We report the fundamental failure of this approach. We analyze exemplarily the Ni-Mn-Ga magnetic shape memory alloy. An applied field results in magnetically induced reorientation of martensitic variants, which form during the phase transformation. This results in a spurious magnetocaloric effect, which only disappears when repeating the measurement. This failure is universal as the vector character of the applied field is not considered in the common scalar evaluation of a Maxwell relation.
机译:在相变附近的弹性,电磁和磁热材料中报道了巨热效应。通常,它们的熵变为麦克斯韦关系间接评估。我们报告了这种方法的根本失败。我们示例性地分析了Ni-Mn-Ga磁形记忆合金。施加的场导致磁诱导的马氏体变体重新定位,在相变期间形成的形成。这导致杂散的磁热效应,这在重复测量时才会消失。这种故障是通用的,因为在麦克斯韦关系的常见标量评估中不考虑所应用的字段的矢量字符。

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