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Effect of white water chemistry on passivation behavior of 304L stainless steel

机译:白色水化学对304L不锈钢钝化行为的影响

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Repassivation kinetics of alloys in particular environment is a crucial property and determines alloy's resistance to pitting, stress corrosion cracking, and erosion-corrosion processes, In this study, the repassivation kinetics of 304L stainless steel in white water environment were investigated using scratch tests the current transients were modeled using a log(i) vs. 1/q relationship. The slope of the linear region was used as an indicator of repassivation rates. Elevated concentrations of chloride and sulfate are found to slow down the repassivation rate. Presence of thiosulfate ions also increase the slope of log(i) vs. 1/q curve. An alteration in repassivation kinetics was observed possibly due to the chemical instability of thiosulfate.
机译:特定环境中合金的重新分配动力学是一个关键的性能,并确定该研究中的合金对蚀,应力腐蚀裂缝和腐蚀腐蚀过程的抵抗力,使用划痕测试电流进行了304L不锈钢在白色水环境中的重新分配动力学使用日志(i)与1 / q关系建模瞬态。线性区域的斜率用作回复率的指标。发现氯化物和硫酸盐浓度升高,以减缓回原因。硫代硫酸盐离子的存在还增加了对数(i)的斜率与1 / q曲线。由于硫代硫酸盐的化学不稳定,可能会观察到重复性动力学的改变。

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